In chemistry, a metal is a chemical element whose atoms readily lose electrons to form positive ions (cations), and form metallic bonds between each other. Metals are sometimes described as a lattice of positive ions surrounded by a cloud of delocalized electrons. They are one of the three groups of elements as distinguished by their ionization and bonding properties, along with the metalloids and nonmetals. On the periodic table, a diagonal line drawn from boron (B) to polonium (Po) separates the metals from the nonmetals. Most elements on this line are metalloids, sometimes called semi-metals; elements to the lower left are metals; elements to the upper right are nonmetals (see the periodic table showing the metals). Metals are usually inclined to form cations through electron loss, reacting with oxygen in the air to form oxides over changing timescales (iron rusts over years, while potassium burns in seconds). Examples: 4Na + O2 → 2Na2O (sodium oxide) 2Ca + O2 → 2CaO (calcium oxide) 4Al + 3O2 → 2Al2O3 (aluminium oxide) The transition metals (such as iron, copper, zinc, and nickel) take much longer to oxidize. Others, like palladium, platinum and gold, do not react with the atmosphere at all. Some metals form a barrier layer of oxide on their surface which cannot be penetrated by further oxygen molecules and thus retain their shiny appearance and good conductivity for many decades (like aluminium, some steels, and titanium). The oxides of metals are generally basic (as opposed to those of nonmetals, which are acidic. Metals in general have high electric, thermal conductivity, luster and density, and the ability to be deformed under stress without cleaving. While there are several metals that have low density, hardness, and melting points, these (the alkali and alkaline earth metals) are extremely reactive, and are rarely encountered in their elemental, metallic form. The majority of metals have higher densities than the majority of nonmetals. Nonetheless, there is wide variation in the densities of metals; lithium is the least dense solid element and osmium is the densest. The metals of groups I A and II A are referred to as the light metals because they are exceptions to this generalization. The high density of most metals is due to the tightly-packed crystal lattice of the metallic structure. The strength of metallic bonds for different metals reaches a maximum around the center of the transition series, as those elements have large amounts of delocalized electrons in a metallic bond. However, other factors (such as atomic radius, nuclear charge, number of bonding orbitals, overlap of orbital energies, and crystal form) are involved as well. The electrical and thermal conductivity of metals originate from the fact that in the metallic bond, the outer electrons of the metal atoms form a gas of nearly free electrons, moving as an electron gas in a background of positive charge formed by the ion cores. Good mathematical predictions for electrical conductivity, as well as the electrons' contribution to the heat capacity and heat conductivity of metals can be calculated from the free electron model, which does not take the detailed structure of the ion lattice into account. An alloy is a mixture of two or more elements in solid solution in which the major component is a metal. Most pure metals are either too soft, brittle or chemically reactive for practical use. Combining different ratios of metals as alloys modifies the properties of pure metals to produce desirable characteristics. The aim of making alloys is generally to make them less brittle, harder, resistant to corrosion, or have a more desirable color and luster. Examples of alloys are steel (iron and carbon), brass (copper and zinc), bronze (copper and tin), and duralumin (aluminium and copper). Alloys specially designed for highly demanding applications, such as jet engines, may contain more than ten elements
Granite is a common and widely occurring type of intrusive, felsic, igneous rock. Granite has a medium to coarse texture, occasionally with some individual crystals larger than the groundmass forming a rock known as porphyry. Granites can be pink to dark gray or even black, depending on their chemistry and mineralogy. Outcrops of granite tend to form tors, and rounded massifs. Granites sometimes occur in circular depressions surrounded by a range of hills, formed by the metamorphic aureole or hornfels. Granite is nearly always massive (lacking internal structures), hard and tough, and therefore it has gained widespread use as a construction stone. The average density of granite is 2.75 g/cm3 and its viscosity at standard temperature and pressure is ~4.5 • 1019 Pa•s The word granite comes from the Latin granum, a grain, in reference to the coarse-grained structure of such a crystalline rock. Granite is classified according to the QAPF diagram for coarse grained plutonic rocks (granitoids) and is named according to the percentage of quartz, alkali feldspar (orthoclase, sanidine, or microcline) and plagioclase feldspar on the A-Q-P half of the diagram. True granite according to modern petrologic convention contains both plagioclase and alkali feldspars. When a granitoid is devoid or nearly devoid of plagioclase the rock is referred to as alkali granite. When a granitoid contains <10% orthoclase it is called tonalite; pyroxene and amphibole are common in tonalite. A granite containing both muscovite and biotite micas is called a binary or two-mica granite. Two-mica granites are typically high in potassium and low in plagioclase, and are usually S-type granites or A-type granites. The volcanic equivalent of plutonic granite is rhyolite. Granite has poor primary permeability but strong secondary permeability. A worldwide average of the average proportion of the different chemical components in granites, in descending order by weight percent, is: SiO2 — 72.04%, Al2O3 — 14.42%, K2O — 4.12%, Na2O — 3.69%, CaO — 1.82%, FeO — 1.68%, Fe2O3 — 1.22%, MgO — 0.71%, TiO2 — 0.30%, P2O5 — 0.12%, MnO — 0.05% Granite is an igneous rock and is formed from magma Granitic magma has many potential origins but it must intrude other rocks. Most granite intrusions are emplaced at depth within the crust, usually greater than 1.5 kilometres and up to 50 km depth within thick continental crust. The origin of granite is contentious and has led to varied schemes of classification. Classification schemes are regional; there is a French scheme, a British scheme and an American scheme. This confusion arises because the classification schemes define granite by different means. Generally the 'alphabet-soup' classification is used because it classifies based on genesis or origin of the magma.
Granite has been extensively used as a dimension stone and as flooring tiles in public and commercial buildings and monuments. Because of its abundance, granite was commonly used to build foundations for homes in New England. The Granite Railway, America's first railroad, was built to haul granite from the quarries in Quincy, Massachusetts, to the Neponset River in the 1820s. With increasing amounts of acid rain in parts of the world, granite has begun to supplant marble as a monument material, since it is much more durable. Polished granite is also a popular choice for kitchen countertops due to its high durability and aesthetic qualities.
Curling stones are traditionally fashioned of Ailsa Craig granite. The first stones were made in the 1750s, the original source being Ailsa Craig in Scotland. Because of the particular rarity of the granite, the best stones can cost as much as US$1,500. Between 60–70 percent of the stones used today are made from Ailsa Craig granite, although the island is now a wildlife reserve and is no longer used for quarrying.
Basalt is a common extrusive volcanic rock. It is usually grey to black and fine-grained due to rapid cooling of lava at the surface of a planet. It may be porphyritic containing larger crystals in a fine matrix, or vesicular, or frothy scoria. Unweathered basalt is black or grey.
The most common uses for this rock are as aggregate in highway construction, railroad ballast, and tile. Basalt is also a major component of asphalt.
On Earth, most basalt magmas have formed by decompression melting of the mantle. Basalt has also formed on Earth's Moon, Mars, Venus, and even on the asteroid Vesta. Source rocks for the partial melts probably include both peridotite and pyroxenite (e.g., Sobolev et al., 2007). The crustal portions of oceanic tectonic plates are composed predominantly of basalt, produced from upwelling mantle below ocean ridges.
The term basalt is at times applied to shallow intrusive rocks with a composition typical of basalt, but rocks of this composition with a phaneritic (coarse) groundmass are generally referred to as dolerite (also called diabase) or gabbro.
The mineralogy of basalt is characterized by a preponderance of calcic plagioclase feldspar and pyroxene. Olivine can also be a significant constituent. Accessory minerals present in relatively minor amounts include iron oxides and iron-titanium oxides, such as magnetite, ulvospinel, and ilmenite. Because of the presence of such oxide minerals, basalt can acquire strong magnetic signatures as it cools, and paleomagnetic studies have made extensive use of basalt.
In tholeiitic basalt, pyroxene (augite and orthopyroxene or pigeonite) and calcium-rich plagioclase are common phenocryst minerals. Olivine may also be a phenocryst, and when present, may have rims of pigeonite. The groundmass contains interstitial quartz or tridymite or cristobalite. Olivine tholeiite has augite and orthopyroxene or pigeonite with abundant olivine, but olivine may have rims of pyroxene and is unlikely to be present in the groundmass.
Alkali basalts typically have mineral assemblages that lack orthopyroxene but contain olivine. Feldspar phenocrysts typically are labradorite to andesine in composition. Augite is rich in titanium compared to augite in tholeiitic basalt. Minerals such as alkali feldspar, leucite, nepheline, sodalite, phlogopite mica, and apatite may be present in the groundmass.
Basalt has high liquidus and solidus temperatures—values at the Earth's surface are near or above 1200 °C (liquidus) and near or below 1000 °C (solidus); these values are higher than those of other common igneous rocks.
The majority of tholeiites are formed at approximately 50–100 km depth within the mantle. Many alkali basalts may be formed at greater depths, perhaps as deep as 150–200 km. The origin of high-alumina basalt continues to be controversial, with interpretations that it is a primary melt and that instead it is derived from other basalt types (e.g., Ozerov, 2000).
Basalt is a common extrusive volcanic rock. It is usually grey to black and fine-grained due to rapid cooling of lava at the surface of a planet. It may be porphyritic containing larger crystals in a fine matrix, or vesicular, or frothy scoria. Unweathered basalt is black or grey.
The most common uses for this rock are as aggregate in highway construction, railroad ballast, and tile. Basalt is also a major component of asphalt.
On Earth, most basalt magmas have formed by decompression melting of the mantle. Basalt has also formed on Earth's Moon, Mars, Venus, and even on the asteroid Vesta. Source rocks for the partial melts probably include both peridotite and pyroxenite (e.g., Sobolev et al., 2007). The crustal portions of oceanic tectonic plates are composed predominantly of basalt, produced from upwelling mantle below ocean ridges.
The term basalt is at times applied to shallow intrusive rocks with a composition typical of basalt, but rocks of this composition with a phaneritic (coarse) groundmass are generally referred to as dolerite (also called diabase) or gabbro.
The mineralogy of basalt is characterized by a preponderance of calcic plagioclase feldspar and pyroxene. Olivine can also be a significant constituent. Accessory minerals present in relatively minor amounts include iron oxides and iron-titanium oxides, such as magnetite, ulvospinel, and ilmenite. Because of the presence of such oxide minerals, basalt can acquire strong magnetic signatures as it cools, and paleomagnetic studies have made extensive use of basalt.
In tholeiitic basalt, pyroxene (augite and orthopyroxene or pigeonite) and calcium-rich plagioclase are common phenocryst minerals. Olivine may also be a phenocryst, and when present, may have rims of pigeonite. The groundmass contains interstitial quartz or tridymite or cristobalite. Olivine tholeiite has augite and orthopyroxene or pigeonite with abundant olivine, but olivine may have rims of pyroxene and is unlikely to be present in the groundmass.
Alkali basalts typically have mineral assemblages that lack orthopyroxene but contain olivine. Feldspar phenocrysts typically are labradorite to andesine in composition. Augite is rich in titanium compared to augite in tholeiitic basalt. Minerals such as alkali feldspar, leucite, nepheline, sodalite, phlogopite mica, and apatite may be present in the groundmass.
Basalt has high liquidus and solidus temperatures—values at the Earth's surface are near or above 1200 °C (liquidus) and near or below 1000 °C (solidus); these values are higher than those of other common igneous rocks.
The majority of tholeiites are formed at approximately 50–100 km depth within the mantle. Many alkali basalts may be formed at greater depths, perhaps as deep as 150–200 km. The origin of high-alumina basalt continues to be controversial, with interpretations that it is a primary melt and that instead it is derived from other basalt types (e.g., Ozerov, 2000).
Basalt is a common extrusive volcanic rock. It is usually grey to black and fine-grained due to rapid cooling of lava at the surface of a planet. It may be porphyritic containing larger crystals in a fine matrix, or vesicular, or frothy scoria. Unweathered basalt is black or grey.
The most common uses for this rock are as aggregate in highway construction, railroad ballast, and tile. Basalt is also a major component of asphalt.
On Earth, most basalt magmas have formed by decompression melting of the mantle. Basalt has also formed on Earth's Moon, Mars, Venus, and even on the asteroid Vesta. Source rocks for the partial melts probably include both peridotite and pyroxenite (e.g., Sobolev et al., 2007). The crustal portions of oceanic tectonic plates are composed predominantly of basalt, produced from upwelling mantle below ocean ridges.
The term basalt is at times applied to shallow intrusive rocks with a composition typical of basalt, but rocks of this composition with a phaneritic (coarse) groundmass are generally referred to as dolerite (also called diabase) or gabbro.
The mineralogy of basalt is characterized by a preponderance of calcic plagioclase feldspar and pyroxene. Olivine can also be a significant constituent. Accessory minerals present in relatively minor amounts include iron oxides and iron-titanium oxides, such as magnetite, ulvospinel, and ilmenite. Because of the presence of such oxide minerals, basalt can acquire strong magnetic signatures as it cools, and paleomagnetic studies have made extensive use of basalt.
In tholeiitic basalt, pyroxene (augite and orthopyroxene or pigeonite) and calcium-rich plagioclase are common phenocryst minerals. Olivine may also be a phenocryst, and when present, may have rims of pigeonite. The groundmass contains interstitial quartz or tridymite or cristobalite. Olivine tholeiite has augite and orthopyroxene or pigeonite with abundant olivine, but olivine may have rims of pyroxene and is unlikely to be present in the groundmass.
Alkali basalts typically have mineral assemblages that lack orthopyroxene but contain olivine. Feldspar phenocrysts typically are labradorite to andesine in composition. Augite is rich in titanium compared to augite in tholeiitic basalt. Minerals such as alkali feldspar, leucite, nepheline, sodalite, phlogopite mica, and apatite may be present in the groundmass.
Basalt has high liquidus and solidus temperatures—values at the Earth's surface are near or above 1200 °C (liquidus) and near or below 1000 °C (solidus); these values are higher than those of other common igneous rocks.
The majority of tholeiites are formed at approximately 50–100 km depth within the mantle. Many alkali basalts may be formed at greater depths, perhaps as deep as 150–200 km. The origin of high-alumina basalt continues to be controversial, with interpretations that it is a primary melt and that instead it is derived from other basalt types (e.g., Ozerov, 2000).
